Brittleness is a mechanical property failure, not a cosmetic streak or a hollow pocket inside the wall.
Brittle injection molded parts break with little plastic deformation. You may hear a sharp snap on ejection, see clean fracture faces on living hinges, or fail customer drop tests while visual inspection still passes. The defect can appear immediately after molding or after storage when degraded resin continues to lose toughness.
Industry references on polymer degradation during molding, including Beaumont Technologies and peer-reviewed work on polyester embrittlement, point to the same mechanism: when covalent bonds along the polymer backbone break, chain length and entanglement drop, and impact strength falls first. Moisture on hydrolyzable resins such as nylon, PBT, PET, and polycarbonate can trigger hydrolysis in the barrel. Thermolysis from high melt temperature, long residence time, and high shear during fill has the same effect on many engineering grades.
For new programs, resin choice and gate strategy should be reviewed in CAD before steel is cut. NetProto returns DFM feedback with instant quotes so teams can reduce degradation and contamination risk while a hardened steel tool is still in planning, depending on part size and complexity.